HOW TO SELECT
AN ESSENTIAL OIL
BY SCOTT BALLARD
(BUYER AND ANALYST OF ESSENTIAL OILS)
Foreword
Scott has a lot of interesting points in how to select a good essential
oil, trying to recognize quality with a whiff of a sample. Most companies
will sell you a sample. In the case of Helichrysum Italicum which
is a rare and a sought after essential oil, most people buy year after
year with the same supplier therefore ensuring their supply for the
following year. There is never enough Helichrysum Italicum to go around,
in fact Brigitte is planting the Flower this year on our land in order
to obtain a constant supply, and we can’t harvest this for 2
years!
I feel that if you are too fussy some people will refuse the sale,
Scott does say to use humour to find the truth and I have to agree
with him there, the language barrier is another factor, should anyone
need some help in French email me at crenacare@orange .com
Have a good read and over to Scott.
Introduction
Even if you go straight to the grower / distiller they may not be
testing their oils. Those that do test most certainly aren't looking
for unwanted phthalates, very few look for pesticides or herbicides.
Very few farmers or distillers know what the chemical composition
should look like. This is not to say that there are not farmers or
distillers out there that are honest and know what they are doing.
If that was the case I wouldn't have a chance and I would have to
grow and distill all the oils I supply, which is almost impossible.
The oils we supply come from all over the world. I'm sorry to say
that only if you know the farmers and/or distillers and are an expert
with a gc-ms testing facility will you get close to the truth of whether
an essential oil is pure or not and the correct chemo-type.
Even if you were to belong to a group which says they are a certifying
body for essential oil companies, even if this certified body test
all there oils and approves them as pure, unless they know the exact
source (where the oils came from and are doing in-depth testing),
they still could be adulterated. There are so many cheap, natural
and synthetic chemicals on the market, so many year to year and origin
to origin variations in essential oils, that sophisticated criminals
can fool the best.
If we think the best possible way to go down is the Pharmaceutical
route, then we would be fooling our selves, as this would lead to
standardization, which in my book is adulteration.
I believe nature should be left alone, as essential oils are evolving.
We all know the strongest are the most diverse in nature. Plants are
weaker against attack when they are standardized. People and animals
get weaker when they are inbred. What makes us think eliminating changes
in oil, add this and that so they are always the same is going to
do anything but help suppliers make more money.
Summary
1.) Best if I buy straight from the grower and/or distiller.
2.) Have a great nose for the oils you purchase.
3.) Do a Gc-Ms (gas chromatography mass spectrum) cross referenced
with your own retention library, with other chemical libraries, with
published data on the specific oil on a period of years from various
sources, chemo types and origins.
4.) Run as many known origin - distillation samples as possible to
judge against.
5.) Look for the ratio % of a number of chemicals within the oil,
including very small peak chemicals and look for the chemicals that
shouldn't be there and should be there.
6.) If you are using a split less injection with Pentane, Acetone
or Ethanol carrier in the test sample to increase column life (acetone
doesn't help column life) you must do a Head Space Analysis ( heat
vile of pure oil and vapours get vacuumed into the Gc-Ms.)
7.) If after all this you even slightly suspect adulteration, synthetic
or not, put sample in suspect archive and don't waste any more time.
Make a note of who sent you the sample and watch them carefully. They
may or may not have done this intentionally.
8.) If you are doing investigative
work or going after a charlatan, (which is unfortunately the norm
with many essential oil companies) please do a Chiral test to see
the enantiomeric distribution % ( chemicals will either have a large
+ or - chirality, but in nature are almost never -50%+50%:which means
its synthetic. Of course you will have to have libraries and information
on chirality to judge against.
Truth is a complex thing, which needs close
examination, which many people don't want to know. What I'm saying
in this letter needs the specifics with the broader picture examined
and revealed. You can take my word, but direct experience, in the
process I live in, will confer my truth. Unless you purchase from
someone like me you have very little chance of knowing if an essential
oil is real.
I have lectured groups of Essential Oil Suppliers and Aroma therapists.
I gave them adulterated Jasmine, Bergamot and Mandarin to Judge against
real unadulterated oils of the "same". They almost always
pick the adulterated ones.
Their comments on why they chose the adulterated oils, " because
they where lighter." or "I liked the smell."
Nature almost always has a depth to it, roundness to it and hopefully
a richness that helps one remember.
What makes a good essential oil and how do you know you’re getting
pure unadulterated oil?
The most important issues in Essential oil for Aromatherapy are purity,
the chemical composition and the Aroma.
So how does one go about the search for purity and composition?
One type of company will ask the price, haggle with another company,
pit the suppliers against each other and buy on price alone. Another
type of company will ask the price, haggle, with another company,
pit the suppliers against each other and asks for samples, smell the
sample and then purchase.
Here are the steps we follow when purchasing oil.
1.) First one must develop open relationships
with growers and distillers, visiting
them, asking for information, having them put it in writing such as
the form below.
* Does your company test on Animals?
* Does the Manufacturer of your Products test on Animals? If so when
the last date was this product was tested on Animals?
* Does this product contain any Animal derived ingredients?
* Does this product contain any mineral oil?
* Does this product contain any thing petroleum derived, i.e.: benzene?
* Is this product plant derived?
2.)Was any natural
or synthetic chemical added to this product, i.e.: linalyl acetate?
If so please list what, give % and description of its function?
* Was anything subtracted from this product, i.e.: nootkatone? If
so what?
* Was anything added to this product? If so what?
* Was your product genetically modified?
* Is this product organically certified?
* Is this product of a Wild Origin, i.e. grown in the wild without
the use of human intervention with the exception of pruning and harvest?
* Is this product of a Natural Farming Origin, i.e. no Artificial
Fertilizer or synthetic pesticides with the exception of natural peritherins?
* Country Origin and Region:
* Latin name:
* Chemo type and method of extraction:
* Date of Manufacture and type of storage:
* Do you store in PVC?
* Get signature.
3.) When speaking to the supplier do you feel they will cut corners?
Ask questions with humour, they will open up more and reveal more
of the truth.
4.) Visit the Plantation or Distillery. One farmer which we buy from
can't understand why the organic farm next to him has no weeds, when
he has to hoe for 100‘s of hours.
5.) If you feel they meet your standards, then ask for a sample and
price. Knowing the market value and the fact if you buy larger quantity
you will pay less per Kg is paramount in giving your end user a good
price. Price if too low is almost always a bad sign and either adulterated
or old. A price that is too high is a supplier playing the perceived
value game. "It's expensive so it must be good."
6.) Once you have the sample you must test it for aroma. You will
need testing strips. The first note is the primary aroma chemical
of the oil. This is not necessarily the largest percentage chemical,
such as in Grapefruit nootkatone is only about 1% of the total oils
components, but has one of the most prominent aromas. A simplified
study of aroma breaks down the oil into three levels: top notes, middle
and base. A highly trained nose will pick out individual chemicals,
such as Linalyl acetate which has a floral cucumber-melon like odour,
an ester as top note. Once one has smelled a chemical in isolation
it is easier to pick them out of the many chemical components of oil.
Such as when you smell a bowl of fruit and isolate the oranges form
the grapefruit. You should then leave the oil on the well mark testing
strip and come back to it in different time periods. These time periods
are determined by the oil tested.
7.) The oil should then have weight per mille Density analyzed. All
oils have a density in relation to water, which we can say is 1. Oils
such as Clove, cinnamon and Myrrh should be >1. Depending on natural
variations such as varieties Myrrh - commiphora myrrha vs. Myrrh -
commiphora mol mol. There are many other reason why the density would
be +or - which I will go into more on a later date.
8.) Then a GC-MS (Gas chromatography- mass
spectroscopy) should be run. A GC is nothing more than a Oven with
a Capillary column 25 - 60 meters in length in it, which the oil is
injected into. The oven then has a temperature setting: as the temperature
rises the lighter more volatile chemicals leave the column and are
hit with an electron beam in the MS. The image of the shattered chemical
is copied onto a electromagnetic plate. The image is then stored in
the computer. After all the chemicals from the oil have been run you
can go into the computer software and match the spectrums against
a library of spectrums. Matches are made with a quality percentage.
Quality matches over 90% are most likely the match, but not always.
This is why you need to run standards of chemicals and develop a library
of with own method (temperature profile, column type same GC-MS)
Once you get good at identifying the individual spectrum patterns
it's like knowing different aromas, but visually.
Don't trust GC analysis alone. Many companies
just use GC without the MS. This is dangerous even if you have a complete
library of standards, which very few people on earth have. GC’s
are good for a cheap and cheerful look at the relative percentages
of components in oil, but they are only analyzed by retention time.
(Retention time: the time a chemical comes out of the GC’s column)
There can be four or five chemicals which have the same retention
time, thus a 1-5 chance of being correct.
What compromises is the supplier willing to make? Brave Heart was
willing to give up his life for freedom. My freedom is to make no
compromise. Truth is what it is. In order to know the truth one must
look at a subject in its entirety. This is not to say a well trained
analyst cannot have good results. It means that quantitative analysis
is better performed in conjunction with Gc-Ms.
Have as many scientific studies of the oils you provide with chemical
data to cross reference. The information on oil is only as good as
the research is. We have found erroneous data on oils from recognized
people in the field of essential oils and Aromatherapy.
8c.) the rule at Kobashi is don't trust one testing method: do them
all. Cross reference is the only sure method to get to the truth.
In this day and age of production and consumption, there is always
a question that must be asked:
What path does the product take and what are the motivations of the
people involved?
What is it that a person wants?
Is that person’s interest in yours?
I believe nature should be left alone, as essential oils are evolving.
We all know the strongest are the most diverse in nature. Plants are
weaker against attack when they are standardized. People and animals
get weaker when they are inbred. What makes us think eliminating changes
in oil, add this and that so they are always the same is going to
do anything but help suppliers make more money.
Scott Ballard
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